## Rajasthan Board RBSE Class 12 Chemistry Chapter 4 Chemical Kinetics

### RBSE Class 12 Chemistry Chapter 4 Text Book Questions

#### RBSE Class 12 Chemistry Chapter 4 Multiple Choice Questions

**RBSE Solutions For Class 12 Chemistry Chapter 4 Question 1.**

The unit of rate constant of zero order reaction will be

(a) mol L^{-1 }s^{-1}

(b) L mol^{-1} s^{-1}

(c) s^{-1}

(d) mol^{2} L^{-1} s^{-1}

**RBSE Solutions For Class 12 Chemistry Question 2.**

The half life of the first order reaction is 69.35, then its rate constant will be

(a) 10^{-2} s^{-1}

(b) 10^{-4} s^{-1}

(c) 10 s^{-1}

(d) 10^{2} s^{-1}

**RBSE Solution Class 12th Chemistry Question 3.**

The rate constant of reaction is 7.239 x 10^{-4} s^{-1}, then the order of reaction will be

(a) 0

(b) 1

(c) 2

(d) 3

**Chemistry Class 12 RBSE Solutions Question 4.**

Which the following statement is true for the first order reaction?

(a) The rate of reaction is directly proportional to zera power of concentration of reactants.

(b) The unit of rate constant is mol L^{-1 }s^{-1}.

(c) The half life of reaction does not depend on initial concentration of reactants.

(d) Can not be say directly.

**Chemistry Class 12 Chapter 4 Question 5.**

On plotting a graph between log K and 1/T for first order reaction. a straight line is obtained. The slope of line will be

(a) – \({ E_{ a } }{ 2.303 }\)

(b) – \({ E_{ a } }{ 2.303R }\)

(c) – \({ 2303 }{ E_{ a }{ R } } \)

(d) – \({ E_{ a } }{ { R } } \)

**Class 12 Chemistry Chapter 4 Solution Question 6.**

The rate of reaction increases rapidly on slightly increase in temperature, because

(a) The number of activated reactants increases.

(b) The number of collisions increases.

(c) The number of free path increases.

(d) Heat of reaction increases.

**RBSE Solution Class 12 Chemistry Question 7.**

Which of the following relationship is correct for zero order reaction?

(a) t_{3/4} = t_{1/2}

(b) t_{3/4} = 1.5 t_{1/2}

(c) t_{3/4} = 0.25t_{1/2}

(d) t_{3/4} = \(\frac { 1 }{ 3 }\)t_{1/2}

**Class 12 Chemistry RBSE Solutions Question 8.**

Arrhenius equation is :

(a) k = – A e^{-Ea/RT}

(b) k = A e^{-Ea/RT}

(c) k = A e ^{Ea/RT}

(d) k = e^{-Ea/RT}

**RBSE Solutions Class 12 Chemistry Question 9.**

The half life of first order reaction is 480s. Then rate constant will be

(a) 1.44 x 10^{-3 }s^{-1}

(b) 1.44 s^{-1}

(c) 0.72 x 10^{-3 }s^{-1}

(d) 2.88 x 10^{-3 }s^{-1}

**RBSE Solutions 12 Chemistry Question 10.**

Time required to complete 90% first order reaction will be

(a) 1.1 times of half life

(b) 2.2 times of half life

(C) 3.3 times of half life

(d) 4.4 times of half life

Answers:

(a) 2. (a) 3. (b) 4. (c) 5.(b) 6. (a) 7. (b) 8. (b) 9. (a) 10. (c)

#### RBSE Class 12 Chemistry Chapter 4 Very Short Answer Type Questions

**RBSE Solutions For Class 12th Chemistry Question 1.**

The rate law for a reaction A + B → product, is given by ; r = k [A]^{\(\frac { 1 }{ 2 }\)} [B]^{2}. What is the order of reaction?

Solution:

Order of reaction = \(\frac { 1 }{ 2 } +2\) = \(2\frac { 1 }{ 2 }\) or 2.5

**RBSE Solutions Chemistry Class 12 Question 2.**

The transformation of the molecule X into Y follows second order kinetics. If the concentration of X increases to three times, how will it affect the rate of formation of Y ?

Solution:

According to question, r_{1} = k[X]^{2 } …(i)

If concentration is increased to three times, then

r_{2} = k [3X]^{2}

r_{2} = k 9 X^{2}

r_{2} = 9k [X]^{2} …(ii)

Divide eq (ii) by eq. (i)

\({ r_{ 2 } }{ r_{ 1 } } =\frac { 9k[X]^{ 2 } }{ k[X]^{ 2 } } \)

\(\frac { r_{ 2 } }{ r_{ 1 } } =9 \)

r_{2} = 9 x r_{ı}

i.e., if concentration is increased there times, the rate increases 9 times.

#### RBSE Class 12 Chemistry Chapter 4 Short Answer Type Questions

**RBSE Chemistry Solution Class 12 Question 1.**

For the reaction R P, the concentration of a reactant changes from 0.03 to 0.22 M in 25 minutes. Calculate the average rate of reaction using units of time both in minutes and seconds.

Solution:

Average rate =

Average rate = 4 x 10^{-4} mol L^{-1} min^{-1}

\({ 4\times 10^{ -4 } }{ 60 } \) mol L^{-1 }s^{-1}

= 6.66 x 10-6 mol L^{-1 }s^{-1}

Hence average rate = 4 x 10^{-4} mol L^{-1} min^{-1}

Average rate = 6.66 x 10^{-6} mol L^{-1 }s^{-1}

**RBSE Solution Chemistry Question 2.**

In a reaction. 2A → Products, the concentration of A decreases from 0.5 mol L^{-1} to 0.4 mol L^{-1} in 10 minutes. Calculate the rate during this interval.

Answer:

For, the reaction,

2A → products

**RBSE Solution 12th Chemistry Question 3.**

The first order reaction has a rate constant 115 x 10^{-3 }s^{-1} How long will 5g of this reactant take to reduce to 3g?

Solution:

For first order reaction,

t = 0.444 x 10^{3}

t = 444 s

**RBSE Class 12 Chemistry Solutions Question 4.**

Time required to decompose SO_{2}Cl_{2} to half of its initial amount is 60 minutes. If the decomposition is of first order reaction, calculate the rate constant for the reaction.

Solution:

t_{1/2} = 60 min

For first order reaction,

k = \(\frac { 0.693 }{ t_{ 1/2 } } \)

= \(\frac { 0.693 }{ 60 }\)

k = 0.01155 min^{-1} = 1.155 x 10^{-2}

\(\frac { 1.155 }{ 60 } \times 10^{ -2 }\) s^{-1}

k = 1.925 x 10^{-4} s^{-1}

**Chemical Kinetics Class 12 Question 5.**

What will be the effect of temperature on rate constant?

Solution:

Rate constant of reaction is nearly doubled with rise in temperature by 10°C. The exact dependance of the rate constant on temperature is given by Arrhenius equation k = Ae^{-Ea/RT} where A is called frequency factor and E_{a} is the activation evergy of the reaction.

T = temperature

R = gas constant.

**RBSE Solution Chemistry Class 12 Question 6.**

The rate of the chemical reaction doubles for an increase of 10K from 298 K. Calculate E_{a}

Solution:

Temperature T_{1} = 298K

Temperature T_{2} = 308K

Rate constant k_{2} = 2 x k_{1}

= 52897.78 J mol

E_{a} = 52.9 kJ / mol

**Class 12th Chemistry RBSE Solutions Question 7.**

The activation energy for the reaction 2HI_{(g)} → H2_{(g)} + 12_{(g)} is 209.5 kJ mol^{-1} at 581 K. Calculate the fraction of molecules of reactants having energy equal to or greater

than activation energy.

Solution:

Fraction of molecules having energy equal to or greater than activation energy

x = Antilog (- 18.8323)

= Antilog 19.1677

x = 1.471 x 10^{-19}

Question 8.

From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.

(i) 3NO_{(g)} → N_{2}O_{(g)} + NO_{2}(g); Rate = k [NO]^{2}

(ii) H_{2}O_{2(ap)} + 3I^{–}_{(aq)} + 2H^{+} → 2H_{2}O_{(l)} + \({ I }_{ 3 }^{ – }\) ; Rate = k[H_{2}O_{2}] [I^{–}]

(iii) CH_{3}CHO_{(g)} + CH_{4(g)} + CO_{(g) }; Rate = k [CH_{3}CHO]_{\(\frac { 3 }{ 2 }\)}

(iv) C_{2}H_{5}Cl_{(g)} → C_{2}H_{4(g)} + HCl_{(g)} ; Rate = k[C_{2}H_{5}Cl]

Solution:

(i) Rate = k [NO]^{2}

Order of reaction = 2

Unit of rate constant = (mol L^{-1})^{1-n} x s^{-1}

n = order of reaction = (mol L^{-1})^{1-2} x s^{-1} = L mol^{-1 }s^{-1}

Hence order of above reaction is 2 and its unit is L mol^{-1} s^{-1}.

(ii) Rate = k [H_{2}O_{g}][I^{–}]

Order of reaction = 1 + 1 = 2

Unit of rate constant = (mol L^{-1})^{1 – n }x s^{-1}

= (mol L^{-1})^{1 – 2} x s^{-1}

= (mol L^{-1}) x s^{-1} = L mol^{-1} x s^{-1}

For the reaction order is 2 and unit of rate constant is L mol^{-1} s^{-1}

(iii) Rate = k (CH_{3}CHO)^{\(\frac { 3 }{ 2 }\)}

Order of reaction= \(\frac { 3 }{ 2 }\)

Unit of rate constant = (mol L^{-1})^{1 – 15 }x s^{-1} = mol^{-1/2 }L^{1/2} s^{-1}

(iv) Rate = k [C_{2}H_{5}CI]

Order of reaction = 1

Unit of rate constant = (mol L^{-1})^{1 – n} x s^{-1} = s^{-1}

Order is 1 and unit is s^{-1}

Question 9.

For the reaction 2A + B → A_{2}B, rate = k [A] [B]^{2} with k = 20 x 10^{-6} mol^{-2 }L^{2} s^{-1}. Calculate the initial rate of the reaction when [A] = 0.1 mol L^{-1} and [B] = 0.2 mol L^{-1} Calculate the rate of reaction after [A] is reduced to 0.06 mol L^{-1}.

Solution:

Initial rate = k [A] [B]^{2}

= 20 x 10^{-6} x 0.1 x (0.2)^{2}

= 8.0 x 10^{-9} mol L^{-1}

When concentration of [A] is reduced from 0.10 mol L^{-1} to 0.06 mol L^{-1 }i.e., 0.04 mol L^{-1} concentration of A is used then used concentration of B is,

\(\frac { 1 }{ 2 } \times 0.04\)

= 0.02 mol L^{-1}

Hence [B] = 0.2 – 0.02

= 0.18 mol L^{-1}

Rate = k [A] [B]^{2}

Rate of reaction = 2.0 x 10^{-6} x 0.06 x (0.18)^{2}

= 3.89 x 10^{-9} mol L^{-1 }s^{-1}

Question 10.

The decomposition of NH_{3} on platinum surface is a zero order reaction. What will be the rate of production of N_{2} and H_{2} when the value of k is 25 x 10^{-4} mol L^{-1} s^{-1}?

Solution:

2 NH_{3} → N_{2} + 3H_{2}

Rate of reaction = \(\frac { 1 }{ 2 } \)(Decrease in concentration of NH_{3})

= (Rate of formation of N_{2})

= \(\frac { 1 }{ 3 } \) (Rate of formation of H_{2})

As the order of reaction is zero hence rate of reaction

= k [NH_{3}]^{0}

= 2.45 x 10^{-4} mol L^{-1 }s^{-1}

Rate of formation of N_{2}

Rate of reaction = Rate of formation of N_{2}

= 2.5 x 10^{-4} mol L s^{-1}

Rate of formation of H_{2}

Rate of reaction = \(\frac { 1 }{ 3 } \) (Rate of formation of H_{2})

Rate of formation of H_{2} = 3 x Rate of reaction

= 3 x 2.5 x 10^{-4}

= 7.5 x 10^{-4} mol L^{-1 }s^{-1}

Question 11.

Mention the factors that affect the rate of a chemical reaction.

Solution:

The factors that affect the rate of a chemical reaction are –

- Concentration :

On increasing concentration of reactants, the probability of colloisions of molecules increases hence rate of reaction increases. - Temperature :

On increasing temperature, the kinetic energy of molecules increases, hence, the number of collision increases. Therefore, the rate of reaction also increases. - Pressure :

On increasing pressure, the molecules of gases come eloser to each other. As a result their collisions increase and hence rate of reaction increases. - Surface Area of Reactants :

On increasing surface area of reactants, the rate of reaction increases. For example, the powdered metals react faster than the metals in a lump. - Nature of reactants :

If the reactants are ionic in nature than the rate of reaction is faster than those in which reactants are molecular in nature.

Question 12.

A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is

(i) doubled

(ii) reduced to \(\frac { 1 }{ 2 } \)?

Solution:

Rate = k [A]^{2} If concentration = a then,

Rate = k (a)^{2}

(i) If concentration is doubled then,

[A] = 2a

(rate)_{1} = k (a)^{2}

(rate)_{2 }= k (2a)^{2}

hence

\(\frac { (rate)_{ 1 } }{ (rate)_{ 2 } } =\frac { k(a)^{ 2 } }{ k(2a)^{ 2 } } \)

\(\frac { (rate)_{ 1 } }{ (rate)_{ 2 } } = { 1 }{ 4 } \)

(rate)_{2} = 4 x (rate)_{1}

i.e., the rate becomes four times.

(ii) If concentration is reduced to half

[A] = \(\frac { a }{ 2 } \)

i.e., rate becomes one fourth.

Question 13.

Following data were obtained for the hydrolysis of ester in water of pseudo order of reaction.

Time (in sec) |
0 | 30 | 60 | 90 |

Ester (mol L^{-1}) |
0.55 | 0.31 | 0.17 | 0.0.85 |

(i) Calculate the average rate of reaction between the time interval 30 to 60 seconds.

(ii) Calculate the pseudo first order rate constant for the hydrolysis of ester.

Solution:

(i) Average rate during the interval 30 – 60 sec

= 4.67 x 10^{-3} mol L^{-1 }s^{-1}

(ii) Rate constant for pseudo first order reaction

= 1.98 x 10^{-2} s^{-1}

Hene rate constant is 1.98 x 10^{-2} s^{-1}

Question 14.

In a reaction between A and B, the initial rate of reaction was measured for different initial concontration of A and B as given below.

A (mol L^{-1}) |
0.20 | 0.20 | 0.40 |

B (mol L^{-1}) |
0.30 | 0.10 | 0.05 |

r (mol L^{-1} s^{-1}) |
5.07 x 10 | 5.10 x 10 | 1.43 x 10 |

What is the order of reaction with respect to A and B?

Solution:

Let the order of reaction w.r.t A is x and w.r.t Bis y.

Then rate law of reaction can be written as

Rate = k[A]^{x} [B]^{y}

With the help of given

(r_{0})_{1} = 5.07 x 10^{-5} = k[0.20]^{x} [0.30]^{y} …(i)

(r_{0})_{2} = 5.07 x 10^{-5} = k[0.20]^{x} [0.10]^{y} ….(ii)

(r_{0})_{3} = 1.43 x 10^{-4} = k(0.40)^{x} [0.05]^{y}. …(iii)

Dividing eq. (i) by (i) we get

1= (3)^{y}

(3)^{0} = (3)^{y}

∴y=0

Diving eq. (iii) by eq. (ii),

y = 0, So, \({ 14.3 }{ 5.07 } =(2)^{ x } \)

Taking logarithm on both sides,

log 2.820 = x log 2

0.4503 = x × 0.3010

or

x = \(\frac { 0.4503 }{ 0.3010 } \) = 1.5

∵ Rate = k[A]^{x} [B]^{y}

∴ Rate = k[A]^{1.5} [B]^{0}

∴ Order of reaction = 1.5 + 0 = 1.5

Hence, order of reaction with respect to Ais 1.5 and with respect to B is 0.

Question 15.

The following results have been obtained during the kinetic studies of the reaction. 2A + B → C + D

Experiment |
[A] mol L^{-1} |
[B] mol L^{-1} |
Initial rate of formation of D (molL^{1}min^{1}) |

I | 0.1 | 0.1 | 6.00 x 10^{-3} |

II | 0.3 | 0.2 | 7.20 x 10^{-2} |

III | 0.3 | 0.4 | 2.88 x 10^{-1} |

IV | 0.4 | 0.5 | 2.40 x-10^{-2} |

What is the rate law ? what is the order with respect to each reactant and the overall order ? Also calculate rate constant and write its unit.

Solution:

Let the equation is,

Rate = k [A]^{x} [B]^{y}

Then According to given datas.

(rate)_{I} = 6.0 x 10^{-3} = k(0.1)^{x} (0.1)^{y}.

(rate)_{II} = 7.2 x 10^{-2} = k(0.3)^{x} (0.2)^{y}

(rate)_{III} = 2.88 x 10^{-1} = k(0.3)^{x }(0.4)^{y}

(rate)_{IV} = 2.40 x 10^{-2} = k(0.4)^{x }(0.1) ^{y}

From equation (2) and (3)

y = 2

From equation (1) and (4)

x=1

Hence, rate = k [A] [B]^{2}

because x = 1, y = 2.

Rate law is

rate = k [A] [B]^{2}

Hence calculation of rate constant with the help of eq (1)

rate = k [A] [B]^{2}

6.0 x 10^{-3} = k(0.1)(0.1)^{2}

k = \(\frac { 6.0\times 10^{ -3 } }{ 10^{ -3 } } \)

k = 6.0 mol^{-2 }L^{2} min^{-1}.

Question 16.

A reaction between A and B is first order w.r.t. A and zero order w.r.t. B. Fill in the blanks in the following table.

Experiment |
[A] /mol L“^{1} |
[B] /mol L“^{1} |
Initial rate / M min^{-1} |

I | 01 | 0.1 | 2.0 x 10^{-2} |

II | – | 0.2 | 40 x 10^{-2} |

HI | 0.4 | 0.4 | – |

IV | – | 0.2 | 2.0 x 10^{-2} |

Solution:

Rate law for the reaction is given as

Rate = k [A]^{1} [B]^{0} = k[A]

From experiment 1, we get

20 x 10^{-2} mol L^{-1} min^{-1} = k [0.1 mol L^{-1}]

(i) In experiment II

Rate = k[A]

[A] = \(\frac { Rate }{ k } \)

(ii) In experiment III

Rate = k[A]

= 0.2 min^{-1} x 0.4 M

= 0.08 M min^{-1} = 8.0 x 10^{-2} M min^{-1}

(iii) In experiment IV

Rate = k[A]

[A] = \(\frac { Rate }{ k } \)

Question 17.

Calculate the half life of first order reaction from their rate constants given below:

(a) 200 s^{-1}

(b) 2 min^{-1}

(c) 4 year^{-1}

Solution:

For first order reaction,

Half life = \(\frac { 0.693 }{ k }\)

(i) t_{1/2} = \(\frac { 0.693 }{ 200 }\) = 3.465 x 10^{-3 }s

(ii) t_{1/2} = 0.3465 min

(iii) t_{1/2} = \(\frac { 0.693 }{ 4 }\) = 0.1732 year

Question 18.

The half life for radioactive decay of ^{14}C is 5730. yr. An archaelogical archetect contained wood that had only 80% of the ^{14}C found in living tree. Estimate the age of the

sample.

Solution:

Radioactive decay follows first order kinetics,

Decay constant (k) = \(\frac { 0.693 }{ t_{ 1/2 } } =\frac { 0.693 }{ 5730 } yr^{ -1 } \)

According to question, living tree has 80% ^{14}C hence,

t =1845 years

Hence the age of sample is = 1845 years

Question 19.

The rate constant for first order reaction is 60 s^{-1} How much time will be required to decompose \(\frac { 1 }{ 16 } th \) part of initial concentration of reactant?

Solution:

For the first order reaction,

t = 4.62 x 10^{-2 }s.

Question 20.

During nuclear explosion, one of the products is ^{90 }Sr with half life of 28.1 years. If 1 µg of ^{70 }Sr was absorbed in bones of a newly born baby instead of calcium, how much of it will remain after 10 year, and 60 years. If it is not lost metabolically?

Solution:

Decay constant (k) = \(\frac { 0.693 }{ t_{ 1/2 } } =\frac { 0.693 }{ 28.1 } \)

0.025 = 25 x 10^{-2} year^{-1}

After 10 years, the left amount will be

[A]_{0} = 1 µg,

[A] = ?

t = 10 years

k = 2.5 x 10^{-2} year^{-1}

log [A] = – 0.1086

[A] = Antilog (- 0.1086)

[A] = 0.78 µg

Hence after 10 years only 0.78 µg will remain.

Calculation of amount left after 60 years.

t= 60 years

[A]_{0} = 1 µg

k= 2.5 x 10^{-2} year^{-1}

[A] = ?

– log [A] = 65.13 x 10^{-2}

– log [A] = 0.6513

[A] = Antilog (-0.6513)

[A] = 0.2232 µg.

After 60 years only 0.2235 µg will remain.

Question 21.

For a first order reaction, show that the time required for 99% completion of a first order reaction is twice the time required for the completion of 90%.

Solution:

Time required for the completion of 99% reaction,

……(1)

Time required for the completion of 90% reaction,

…… (2)

Divide eq. (1) eq. (2)

t_{99%} = 2 x t_{90%}

Question 22.

A first order reaction takes 40 min for 30% decomposition. Calculate t_{1/2}.

Solution:

Question 23.

For the decompostion of azoisopropane to hexane and nitrogen at 543 K, the following data is obtained

t (sec) |
p ( mm of Hg) |

0 | 35.0 |

360 | 54.0 |

720 | 63.0 |

Calculate the rate constant.

Solution:

(CH_{3})_{2} CHN = NCH(CH_{3})_{2(g)} → N_{2(g)} + C_{6}H_{14(g)}

Suppose p_{i} is the initial pressure at t = 0

After time t say x mole of azoisopropane decomposes and the pressure is p.

(CH_{3})_{2} CHN = NCH(CH_{3})_{2} → N_{2} + C_{6}H_{4}

Intial pressure (at t = 0) Pi 0 0

pressure at time = t P_{i} – x x x

The rate constant at 360 s,

P_{i} = 35.0 mm

At time t, p = p_{i} – x + x + x = P_{i} + x

x = p – P_{i} = 54 – 35 = 19.0 mm

Now p at time 360_{s} = 35 – 19.0 = 16 mm

= 2.17 x 10_{-3 }s^{-1}

Similarly x = p- pi = 63 – 35 = 28 mm

p at time 720 sec = 35 – 28 = 7 mm

= 2.235 x 10^{-3 }s^{-1}

Question 24.

The following data were obtained during the first order thermal decomposition of SO_{2}Cl_{2} at a constant volume.

SO_{2}Cl_{2(g)} → SO_{2(g)} + Cl_{2(g)}.

Experiment |
Time/ s |
Total pressure/ atm |

1 | 0 | 0.5 |

2 | 100 | 0.6 |

Calculate the rate of reaction when total pressure is 0.65 atm.

Solution:

SO_{2}Cl_{2(g)} → SO_{2(g)} + Cl_{2(g)}

Total pressure after time ‘t

P_{t} = (P_{0} – x) + x + x

P_{t} = P_{0} + x

x = P_{t} – P_{0}

Initial pressure = P_{0}

Final pressure = P_{0} – x

= P_{0} – (P_{t} – P_{0})

= 2P_{0 }– P_{t}

k=2.2316 x 10^{-3}s^{-1}

P_{t} = 0.65 atm

i.e., (P_{0} + P)= 0.65 atm

P=0.65 – P_{0} = 0.65 – 0.50

P= 0.15 atm

Pressure of SO_{2}Cl_{2} at time t

P_{SO2}_{Cl2} = P_{0} – P

= 0.50 – 0.15

= 0.35 atm

At time ‘t

Rate = k x P_{SO2}_{Cl2}

= 2.2316 x 10^{-3} x 0.35

= 7.8 x 10^{-4} atm s^{-1}

Hence when total pressure is 0.65 atm then the rate will be 7.8 x 10^{-4} atm s^{-1}

Question 25.

The rate constant for the decompositon of N_{2}O_{5} at various temperature is given below.

T^{o}/c |
a |
20 |
40 |
60 |
80 |

10^{-5 }x klis-^{1} |
0.0787 | 1.70 | 25.7 | 178 | 2140 |

Draw a graph between In k and \(\frac { 1 }{ T } \) and calculate the values of A and E_{a}. Predict the rate constant at 30°C and 50°C

Solution:

For plotting curve between log k and \(\frac { 1 }{ T } \), we have to prepare this table.

T (K) |
273 |
293 |
313 |
333 |
353 |

\(\frac { 1 }{ T } \) |
0.003663 | 0.003413 | 0.003195 | 0.003003 | 0.002833 |

Ks-^{1} |
0.0787 x 10^{-5} |
1.70 x 10^{-5} |
25.7 x 10^{-5} |
178 x 10″^{5} |
2140 x 10^{-5} |

logk | – 6.1040 | – 47696 | – 3.5901 | – 27496 | – 1.6996 |

A curve plotted with the help of above values is as follows.

= 97772.64J mol^{-1}

= 97.772 kJ mol^{-1}

We know that,

Compare the above equation with y = mx + c then,

log A = C at ‘y’ axis i.e., value of k on axis.

log A = ( -1+ 7.2) = 6.2

y_{2} – y_{1} = – ( -7.2)

Frequency (A) factor = antilog 6.2

= 1585000

= 1.585 x 10^{6} collisions s^{-1}

Value of k can be calculated with the help of curve.

T |
1/T |
Value of log k from graph |
Value of k |

303 K | 0.003300 | – 4.2 | 6.31 x 10^{-5 }s^{-1} |

232 K | 0.003096 | – 2.8 | 1.585 x 10^{-2} s^{-1} |

Question 26.

The rate constant for the decomposition of a hydrocarbon is 2.418 x 10^{-5 }s^{-1} at 546 K. If the energy of activation is 179.9 kJ/mol, what will be the value of pre-exponential factor? Solution:

k = 2.418 x 10^{-5 }s^{-1}

E_{a} = 179.9 kJ/mol

= 179.9 x 10^{3} J/mol

T = 546K

Hence according to Arrhenius equation

= (- 5 + 0.3834) + 17.2081

= 12.5924 s^{-1}

A = Antilog (12.5924)

A = 3.912 x 10^{12} s^{-1}

Hence the value of pre-exponential factor is

3912 x 10^{12} s^{-1}.

Question 27.

Consider a certain reaction A → Products with k= 20 x 10^{-2 }s^{-2}. Calculate the concentration of A remaining after 100 s if the initial concentration of A is 1.0 mol L^{-1}.

Solution:

k = 20 x 10^{-2 }s^{-1}

[A]_{0} = 1.0 mol L^{-1}

t = 100s

[A] = ?

– log [A] = 0.8684

log[A] = – 0.8684

[A] = Antilog (-0.8684)

or [A] = Antilog (1.1316)

[A] = 0.1354 mol L^{-1}

Hence after 100s, the remaining amount of concentration will be 0.1354 mol L^{-1}

Question 28.

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with t_{1/2} = 3.00 hours. What fraction of the sample of sucrose remains after 8 hours?

Solution:

For a first order reaction

Let the initial concentratiorn is 1mol/L, then

[A]_{0} = 1

\(\frac { [A]_{ 0 } }{ [A] }\) = 6.345

\(\frac { 1 }{ [A] }\) = 6.345

[A] = \(=\frac { 1 }{ 6.345 }\)

[A] = 0.158 mol/L

Hence after 8 hours 0.158 M sucrose will remain.

Question 29.

The decomposition of a hydrocarbon follows the equation k= (45 x 10^{11}s^{-1})e^{-28000 k/T} Calculate activation energy (E_{a}).

Solution:

According to Arrhenius equation,

k= Ae^{-Ea/RT} …. (1)

According to equation

k= (4.5 x 10^{11 }s^{-1})e^{-28000 k/T} …..(2)

Compare equation (1) and (2)

\(-\frac { Ea }{ RT } =\frac { -28000K }{ T }\)

or E_{a} = 28000 K x R

or E_{a} = 28000 K x 8.314J K^{-1}mol^{-1}

E_{a} = 232792 J/mol

E_{a} = 232.79 kJ/mol

The activation energyis 232.79 kJ/mol

Question 30.

The rate constant for the first order decompostion of H_{2}O_{2} is given by the following eqaution:

log k = 14.34 – 125 x 10^{4} KT

Calculate E_{a} for this reaction and at what temperature will its t_{1/2} be 256 minutes?

Solution:

According to Arrhenius equation,

T = 669K

Hence temperature = 669 K

Question 31.

The decomposition of A into products has value of kas 4.5 x 10^{3 }s^{-1} at10°C and energy of activation is 60 kJ mol^{-1}. At what temperature would kbe 15 x 10^{4} s^{-1}?

Solution:

k_{1} = 4.5 x 10^{3}s^{-1}

T_{1} = 10 + 273 = 283 K

k_{2} = 1.5 x 10^{4} s^{-1}

T_{2} = ?

E_{a} = 60 kJ/mol = 60 x 10^{3} J/mol

According to Arrhenius equation,

or 0.0472 T_{2} = T_{1} – 283

or T_{1} – 0.0472 T_{2} = 283

or 0.9528 T_{2} = 283

T_{2} = \(\frac { 283 }{ 0.9528 }\) = 297 K

Hence temperature = 297 K

Question 32.

The time required for 10% completion of a first order reaction at 298 K is equal to that required for its 25% completion at 308 K. If the value of A is 4 x 10^{10 }s^{-1}, Calculate the value of k at 318 K and E_{a}.

Solution:

= 10.6021 – 12.5843= – 1.9822

k = Antilog (-1.9822) = Antilog (2.0178)

k = 1.042 x 10^{-2 }s^{-1}

Question 33.

The rate of a particular reaction quadruples on increasing temperature from 293 K to 313 K. For this reaction, calculate activation energy.

Solution:

According to question,

= 528545 J mol^{-1}

E_{a} = 52.854 kJ mol^{-1}.

### RBSE Class 12 Chemistry Chapter 4 Long Answer Type Question

Question 1.

The decompostion of dimethyl ether leads to the formation of CH_{4}, H_{2} and CO and the reaction rate is given by, Rate = k [P_{CH3OCH3}]^{3/2}. If the pressure is measured in bar and time in minutes, then what are the units of the rate and rate constant?

Answer:

CH_{2}OCH_{3} → CH_{4} + H_{2} + CO

Question 2.

What is the effect of temperature on the rate constant of a reaction? How can this temperature effect on the rate constant be represented quantitatively?

Answer:

The rate constant of a reaction increases with increase of temperature and becomes nearly double for every 10° rise of temperature. The effect can be represented quantitatively by Arrhenius equation,

k = Ae^{-Ea/RT}

Where,

A = Arrhenius constant

E_{a} = Activation energy

R = Gas constant

T = Temperature

k = Rate Constant

Question 3.

A reaction is of first order with respect to A and second order with respect to B.

(i) Write differential rate equation.

(ii) How is the rate affected when the concentration of B is trippled?

(iii) How is the rate affected when the concentration of both A and B is doubled.

Answer:

(i) Rate of reaction

\(\frac { dx }{ dt } \) = k[A] [B]2

(ii) Let[A] = a, [B] = b

If [B] is increases three times

[B] = 3b

then,

rate = k[A] [B]^{2}

rate_{1} = k × a × b^{2} ….(1)

rate_{2} = k x a x (3b)^{2} …(2)

from eq (1) and (2)

(rate)_{2} = 9 x (rate)_{1}

The rate becomes nine times.

(iii) (rate) = k[A] [B]^{2}

(rate)_{1} = k x a x b^{2}

(rate)_{2} = k x (2a) x (2b)_{2}

(rate)2 = 8 (rate)_{1}

The rate becomes eight times.

Question 4.

The experimental data for decomposition of N_{2}O_{5} [2N_{2}O_{5} → 4NO_{2} + O_{2}] in gas phase at 318 K are given below:

Time/s1O^{2} x[N_{2} O_{5} ]/molL^{-1} |
0 1.63 |
400 1.63 |
800 1.14 |
1200 0.93 |
1600 0.78 |

Time/s10^{2}x[N_{2}O_{5}]/molL^{-1} |
2000 0.64 |
2400 0.53 |
2800 0.43 |
3200 0.35 |

(i) Plot (N_{2}O_{5}) aganist t.

(ii) Find the half life period for the reaction.

(iii) Draw a graph between log (N_{2}O_{5}) and t.

(iv) What is the rate law ?

(v) Calculate the rate constant.

(vi) Calculate the half life period from k and compare it with answer (ii).

Answer:

t(s) |
0 | 400 | 800 | 1200 | 1600 | 2000 | 2400 | 12600 | 3200 |

[N_{2}O_{5}J(mol L^{-1}) |
1.63 | 1.36 | 1.14 | 0.93 | 10.78 | 0.64 | 0.53 | 10.43 | 0.35 x l0^{-2} |

log N_{2}O_{5} |
-1.79 | -1.87 | – 1.94 | -2.03 | 2.11 | -2.19 | -2.28 | 1-2.37 | -2.46 |

(i) Plot (N_{2}O_{3}) aganist t

(ii) Half life period (t_{1/2}) for the given reaction is the time during which initial concentration of N_{2}O_{5} changes from 1.63 x 10^{-2} M to half this value i.e. to 0.815 x 10^{-2} M and in the graph it has been shown to be 1440 s.

(iii) Graph between log [N_{2}O_{5}] and time t.

(iv) Since a straight line is observed when log [N_{2}O_{5}] is plotted against time, therefore the reaction is of first order.